Metal-Organic Chemical Vapor Deposition Precursors: Diagnostic Check for Volatilization Thermodynamics of Scandium(III) β-Diketonates
نویسندگان
چکیده
Scandium complexes with β-diketonate ligands are valuable precursors for the metal–organic chemical vapor deposition (MOCVD) of scandia based materials, but data on their volatilization thermodynamics crucial to MOCVD technology in a huge disarray. We have addressed this issue diagnostic tool principles group additivity and structure–property relationships, which had been developed by us specifically objects. For purpose, mass experimental pressures enthalpies sublimation, vaporization fusion available literature scandium(III) β-diketonates has compiled analyzed. Additionally, saturated thermodynamic sublimation characteristics obtained acetylacetone, hexafluoroacetylacetone, 3-methyl-2,4-pentanedione transpiration thermogravimetric methods. New allowed arbitrate conflict data. As result, consistent set three discussed processes eight scandium complexes. Dispersion interactions non-additive effects shown be typical metal tris-β-diketonates. They taken into account improve check. It is now possible quite easily assess tris-β-diketonate different metals demand as gas-phase technology.
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ژورنال
عنوان ژورنال: Coatings
سال: 2023
ISSN: ['2079-6412']
DOI: https://doi.org/10.3390/coatings13030535